High-Efficiency Synthesis and Properties of Latent Pigment Red 272DPP-BOC by Microwave Irradiation

Authors: Tomoji Ohishi, Yu Kimura, Kiyohiko Nakajima, Masayuki Watanabe, Noboru Aoyagi

ABSTRACT
A high-efficiency synthesis method for a latent pigment of red pigment diketo-pyrrolo-pyrrole (Pig. Red 272:272DPP), which is important as a functional organic pigment, was investigated, and the investigation results revealed that irradiation of microwaves (MWs) for several seconds to 272 DPP in NMP (N-methyl-2-pyrrolidone) solvent yielded DPP latent pigment (272DPP-BOC) at a high yield of 86.2%. Two kinds of latent-pigment crystals, namely, red and yellow, were obtained by recrystallization, and it was found that the fluorescence-emission properties of the two kinds differ significantly. Single-crystal X-ray structural analysis showed that the difference in the fluorescence-emission properties of the two types is derived from the difference in their crystal structures.

Source:

Journal: Materials Sciences and Applications
DOI: 10.4236/msa.2020.113013 (PDF)
Paper Id: 98763 (metadata)

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